Use of electrochemical technology to increase the quality of the effluents of bio-oxidation processes. A case studied

In this work, it has been studied the use of conductive-diamond electrochemical oxidation (CDEO) as a refining technology to assure the quality of the effluents of door manufacturing processes (DMP). To do this, the raw effluents of these factories have been treated by a combination of physicochemical, biological and CDEO treatments. CDEO was found to be a feasible alternative to the refinement of a wooden DMP waste. It can successfully decrease the organic load of the effluents of the biological oxidation with low energy requirements. In addition, in case of incidents in the biological process, CDEO can treat successfully the effluents of the coagulation process. The effluents of the biological treatment have also been treated by CDEO in order to check the possible use of electrochemical technology to increase the biodegradability of the effluents and their possible recycle to the biological treatment. Unfortunately, electrochemical technology was found to be not adequate to increase the biodegradability of the effluents of a biological treatment. The hard oxidation conditions generated during CDEO do not lead to the accumulation of intermediates but to the almost direct formation of carbon dioxide. Lowering the current density or changing the electrodes can not enhance the biodegradability of the effluents of an electrochemical cell.     

Stochastic Transfer Function Model and Neural Networks to Estimate Soil Moisture1

Abstract: A practical methodology is proposed to estimate the three‐dimensional variability of soil moisture based on a stochastic transfer function model, which is an approximation of the Richard’s equation. Satellite, radar and in situ observations are the major sources of information to develop a model that represents the dynamic water content in the soil. The soil‐moisture observations were collected from 17 stations located in Puerto Rico (PR), and a sequential quadratic programming algorithm was used to estimate the parameters of the transfer function (TF) at each station. Soil texture information, terrain elevation, vegetation index, surface temperature, and accumulated rainfall for every grid cell were input into a self‐organized artificial neural network to identify similarities on terrain spatial variability and to determine the TF that best resembles the properties of a particular grid point. Soil moisture observed at 20 cm depth, soil texture, and cumulative rainfall were also used to train a feedforward artificial neural network to estimate soil moisture at 5, 10, 50, and 100 cm depth. A validation procedure was implemented to measure the horizontal and vertical estimation accuracy of soil moisture. Validation results from spatial and temporal variation of volumetric water content (vwc) showed that the proposed algorithm estimated soil moisture with a root mean squared error (RMSE) of 2.31% vwc, and the vertical profile shows a RMSE of 2.50% vwc. The algorithm estimates soil moisture in an hourly basis at 1 km spatial resolution, and up to 1 m depth, and was successfully applied under PR climate conditions.     

Managers as drivers of CSR in state-owned enterprises

Corporate social responsibility (CSR) is increasingly required not only of private sector companies, but also of state-owned enterprises (SOEs), whose main function is to provide services to society and not principally to obtain financial reward. The important role played by managers in implementing CSR has been demonstrated by prior research. The objective of this paper is to examine how managers of SOEs perceive the concept of CSR, the reasons for their involvement and how it is integrated into everyday business practices. In addition, we examine whether managers' attitudes towards CSR policies are influenced by their personal profiles and by the sector in which the SOEs work. We find that, although these managers are aware of the importance of the CSR principles underlying their activities and understand the meaning, scope and dimensions of CSR, there remains an evident need to enhance the application of CSR policies among the strategies of SOEs. The manager profile and the sector in which the SOEs work both have a strong influence on their behaviour regarding CSR issues.     

Microbial biomass governs enzyme activity decay during aging of worm-worked substrates through vermicomposting

Vermicomposting is the biooxidation and stabilization of organic matter involving the joint action of earthworms and microorganisms, thereby turning wastes into a valuable soil amendment called vermicompost. Studies have focused on the changes in the type of substrates available before and after vermicomposting, but little is known on how these changes take place, especially those changes related with maturation of vermicompost. This study investigated the effects of aging on the microbiological properties of fresh vermicompost produced from pig slurry by analyzing the substrate after the earthworms had left it. We incubated 16-wk-old vermicompost and sampled it after 15, 30, 45, and 60 d analyzing microbial biomass and activity (assessed as microbial biomass N and basal respiration respectively) and four enzymatic activities (beta-glucosidase, cellulase, protease, and alkaline phosphatase). Aging of vermicompost resulted in decreases of microbial biomass and activity. Three of the four enzymes analyzed also showed decrease. An initial increase followed by a rapid decrease in alkaline phosphatase was also recorded. High and significant correlations between microbial biomass and beta-glucosidase (r = 0.62, P < 0.001), cellulase (r = 0.56, P < 0.01), and protease (r = 0.82, P < 0.001) were found. Results suggest that there may be two steps involved in the aging dynamics of vermicompost with regards to extracellular enzyme activity; the first step was characterized by a decrease in microbial populations, which resulted in a reduction in the synthesis of new enzymes. The second step was the degradation of the pool of remaining enzymes. This dynamic does not seem to be affected by earthworms because similar decaying patterns of microbial biomass and activity were found in substrate where earthworms were present.     

Waste materials for activated carbon preparation and its use in aqueous-phase treatment: a review

Commercial activated carbon is a preferred adsorbent for the removal of micropollutants from the aqueous phase; however, its widespread use is restricted due to high associated costs. To decrease treatment costs, attempts have been made to find inexpensive alternative activated carbon (AC) precursors, such as waste materials. Some reviews report the use of waste materials for the preparation of AC; however, these studies are restricted to either type of wastes, preparation procedures, or specific aqueous-phase applications. The present work reviews and evaluates literature dedicated both to the preparation of AC by recycling different types of waste materials and also to its application in various aqueous-phase treatments. It is clear that conventional (from agriculture and wood industry) and non-conventional (from municipal and industrial activities) wastes can be used to prepare AC, that can be applied in various aqueous treatment processes, namely to remove organic pollutants, dyes, volatile organic compounds, and heavy metals. Moreover, high surface areas can be obtained using either physical or chemical activation; however, combined treatments might enhance the surface properties of the adsorbent, therefore increasing its adsorption capacity. It is evident from the revision made that AC prepared from both conventional and non-conventional wastes might effectively compete with the commercial ones. This happens mostly when the activation procedures are optimized considering both the raw material used to produce the carbons and the contaminants to be removed.     

Water distribution system failure: a framework for forensic analysis

The main purpose of a water distribution system (WDS) is to deliver safe water of desirable quality, quantity and continuity to consumers. However, in many cases, a WDS fails to fulfill its goal owing to structural and associated hydraulic failures and/or water quality failures. The impact of these failures can be reduced significantly if preventive actions are taken based on their potential of occurrences or if a failure occurs and is detected within a minimum period of time after its occurrence. The aim of this research was to develop a forensic system for WDS failures. As part of the proposed forensic analysis, a framework has been developed, which investigates structural and associated hydraulic failures as well as water quality failures and integrates all failure investigation under a single platform. Under this framework, four different models have been developed to evaluate and identify structural and associated hydraulic failures and water quality failures. If a failure is detected in the system, the framework is capable of identifying the most probable location of the failure. To investigate the effectiveness of the proposed framework, the developed models have been tested and implemented in different WDSs.     

Particulate matter levels in a South American megacity: the metropolitan area of Lima-Callao,Peru

The temporal and spatial trends in the variability of PM₁₀ and PM_2.5 from 2010 to 2015 in the metropolitan area of Lima-Callao, Peru, are studied and interpreted in this work. The mean annual concentrations of PM₁₀ and PM_2.5 have ranges (averages) of 133–45 μg m^?3 (84 μg m^?3) and 35–16 μg m^?3 (26 μg m^?3) for the monitoring sites under study. In general, the highest annual concentrations are observed in the eastern part of the city, which is a result of the pattern of persistent local winds entering from the coast in a south-southwest direction. Seasonal fluctuations in the particulate matter (PM) concentrations are observed; these can be explained by subsidence thermal inversion. There is also a daytime pattern that corresponds to the peak traffic of a total of 9 million trips a day. The PM_2.5 value is approximately 40% of the PM₁₀ value. This proportion can be explained by PM₁₀ re-suspension due to weather conditions. The long-term trends based on the Theil-Sen estimator reveal decreasing PM₁₀ concentrations on the order of ?4.3 and ?5.3% year^?1 at two stations. For the other stations, no significant trend is observed. The metropolitan area of Lima-Callao is ranked 12th and 16th in terms of PM₁₀ and PM_2.5, respectively, out of 39 megacities. The annual World Health Organization thresholds and national air quality standards are exceeded. A large fraction of the Lima population is exposed to PM concentrations that exceed protection thresholds. Hence, the development of pollution control and reduction measures is paramount.     

The response of sea scallop (Placopecten magellanicus) veligers to a weak thermocline in 9-m deep mesocosms

We examined the vertical distributions of scallop (Placopecten magellanicus) veligers in deep (0.6 m diameter, 9.5 m deep) polyethylene mesocosms from December 1991 to January 1992. In the mesocosms temperature stratification varied from 0 to 1.5 °C. Profiles of vertical distribution revealed several repeated patterns. Peaks in veliger numbers often appeared at the water surface and just above the thermocline. Higher density patches were seen below the surface peaks, and revealed the presence of bio-convective cells. Distribution away from these discontinuities was usually even. Distribution of veligers was affected by thermoclines above 1.0 °C. Responses to thermoclines varied with larval age and time of day, and 28 to 30 d veligers passed in both directions through a 1.5 °C thermocline. We conclude that larval behaviour is a major determinant of whether veligers pass through a thermocline. Kinematic viscosity may play a role in perception of temperature changes. Two potential consequences of such behaviour are (1) remaining in more productive upper water layers, where feeding opportunities are enhanced, and (2) increased horizontal transport in the region of the thermocline, which may enhance recruitment. Received: 15 May 1996 / Accepted: 11 May 2000